Poly(tetrafluoropropyl methacrylate)

Poly(tetrafluoropropyl methacrylate)

Poly(2,2,3,3-tetrafluoropropyl methacrylate)

NAMES AND IDENTIFIERS OF POLYMER

POLYMER CLASS	Polymethacrylate
COMMON NAMES	Poly(2,2,3,3-tetrafluoropropyl methacrylate)
STRUCTURE BASED NAME	Poly(2,2,3,3-tetrafluoropropyl 2-methylpropenoate)
ACRONYMS
CAS #
CurlySMILES	C{-}C{n+}(C)(C(=O)OCC(F)(F)C(F)F

IDENTIFIERS OF MONOMER(S)

CAS #	45102-52-1
COMMON NAMES	2,2,3,3-Tetrafluoropropyl methacrylate
SMILES	FC(F)C(F)(F)COC(=O)C(=C)C
Std. InChI	InChI=1S/C7H8F4O2/c1-4(2)5(12)13-3-7(10,11)6(8)9/h6H,1,3H2,2H3
Std. InChIKey	RSVZYSKAPMBSMY-UHFFFAOYSA-N
STRUCTURE

Thermo-Physical Properties: Experimental / Literature Data

PROPERTY	UNIT	VALUE / RANGE	PREFERRED
Molar Volume V_m	mL mol^-1	122.5
Density ρ	g mL^-1	1.52
Solubility Parameter δ	MPa^1/2
Molar Cohesive Energy E_coh	J mol^-1
Glass Transition Temperature T_g	K	339 - 353	344
Molar Heat Capacity C_p	J (mol K)^-1
Entanglement Molecular Weight M_e	g mol^-1
Index of Refraction n	none	1.417 - 1.422	1.42

Thermo-Physical Properties: Calculated Data

PROPERTY	UNIT	VALUE / RANGE	PREFERRED
Molecular Weight of Repeat unit	g mol^-1	186.1
Van-der-Waals Volume V_vW	mL mol^-1	74.0
Molar Volume V_m	mL mol^-1	114.8 - 122.5	119.3
Density ρ	g mL^-1	1.52 - 1.58	1.54
Solubility Parameter δ	MPa^1/2	15.6- 16.7	16.2
Molar Cohesive Energy E_coh	J mol^-1	33600 - 37000	35200
Glass Transition Temperature T_g	K	337- 345	341
Molar Heat Capacity C_p	J (mol K)^-1	195 - 249	233
Entanglement Molecular Weight M_e	g mol^-1	25400 - 32800	29000
Index of Refraction n	none	1.41 - 1.43	1.42

Last updated: October 25, 2015

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